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SAF
2507® (UNS S32750) - A 25Cr
Duplex Stainless Steel |
Applications
| Standards | Corrosion
Resistance | Chemical Analysis
Mechanical Properties | Processing
| Welding
|
Click here to
download 2507 PDF file |
| Alloy SAF 2507
is a super duplex stainless steel with 25% Chromium, 4%
Molybdenum, 7% Nickel designed for demanding applications
which require exceptional strength and corrosion resistance,
such as chemical process, petrochemical and seawater equipment.
The steel has excellent resistance to chloride stress corrosion
cracking, high thermal conductivity and a low coefficient
of thermal expansion. The high chromium, molybdenum and
nitrogen levels provide excellent resistance to pitting,
crevice and general corrosion.
The impact strength is also high. Alloy SAF 2507 is not
recommended for applications which require long exposures
to temperatures above 570ÅF because of the risk of a reduction
in toughness.
|
Applications
- Oil and gas industry equipment
- Offshore platforms, heat exchangers,
process and service water systems, fire-fighting systems,
injection and ballast water systems
- Chemical process industries,
heat exchangers, vessels, and piping
- Desalination plants, high pressure
RO-plant and seawater piping
- Mechanical and structural components,
high strength, corrosion-resistant parts
- Power industry FGD systems,
utility and industrial scrubber systems, absorber towers,
ducting, and piping
|
| Standards
ASTM/ASME .......... A240 - UNS S32750
EURONORM............ 1.4410 - X2 Cr Ni MoN 25.7.4
AFNOR.................... Z3 CN 25.06 Az
|
Corrosion
Resistance
General Corrosion
The high chromium and molybdenum content of SAF 2507 make
it extremely resistant to uniform corrosion by organic acids
like formic and acetic acid. SAF 2507 also provides excellent
resistance to inorganic acids, especially those containing
chlorides.
In dilute sulfuric acid contaminated with chloride ions, SAF
2507 has better corrosion resistance than 904L, which is a
highly alloyed austenitic steel grade specially designed to
resist pure sulfuric acid.
Stainless steel of type 316L (2.5%Mo) cannot be used in hydrochloric
acid due to the risk of localized and uniform corrosion. However,
SAF 2507 can be used in dilute hydrochloric acid. Pitting
need not be a risk in the zone below the borderline in this
figure, but crevices must be avoided. 
Isocorrosion curves, 0.1 mm/year, in sulfuric acid
with an addition of 2000 ppm chloride ions

Isocorrosion curves, 0.1 mm/year, in hydrochloric acid.
Broken line curve represents the boiling point
Critical Pitting Temperature (CPT) range for
various alloys in 1M NACl

Critical Crevice Corrosion Temperature (CCT)
for various alloys in 10% FeCl3
Intergranural Corrosion
SAF 2507’s low carbon content greatly lowers the risk
of carbide precipitation at the grain boundaries during
heat treatment; therefore, the alloy is highly resistant
to carbide-related intergranular corrosion.
Stress Corrosion Cracking
The duplex structure of SAF 2507 provides excellent resistance
to chloride stress corrosion cracking (SCC).
Because of its higher alloy content, SAF 2507 is superior
to 2205 in corrosion resistance and strength. SAF 2507 is
especially useful in offshore oil and gas applications and
in wells with either naturally high brine levels or where
brine has been injected to enhance recovery.
Pitting Corrosion
Different testing methods
can be used to establish the pitting resistance of steels
in chloride-containing solutions. The data above were measured
by an electrochemical technique based on ASTM G 61. The
critical pitting temperatures (CPT) of several high-performance
steels in a 1M sodium chloride solution were determined.
The results illustrate the excellent resistance of SAF 2507
to pitting corrosion. The normal data spread for each grade
is indicated by the dark gray portion of the bar
Crevice Corrosion
The presence of crevices,
almost unavoidable in practical constructions and operations,
makes stainless steels more susceptable to corrosion in
chloride enviroments. SAF 2507 is highly resistant to crevice
corrosion. The critical crevice corrosion temperature of
SAF 2507 and several other high-performance stainless steels
are shown above.
|
Chemical
Analysis
Typical
values (Weight %)
| C |
Cr |
Ni |
Mo |
N |
Others |
| 0.020 |
25 |
7 |
4.0 |
.27 |
S=0.001 |
| PREN = [Cr%] + 3.3 [Mo%] +
16 [N%] ≥ 40 |
|
|
Mechanical Properties
Mechanical
and Physical Properties
SAF 2507 combines high tensile and impact strength with
a low coefficient of thermal expansion and high thermal
conductivity. These properties are suitable for many structural
and mechanical components. The low, ambient, and elevated
temperature mechanical properties of SAF 2507 sheet and
plate are shown below. All of the test data shown are for
samples in the annealed and quenched condition.
SAF 2507 is not recommended for applications which require
long exposures to temperatures in excess of 570ÅF because
of the increased risk of a reduction in toughness. The data
listed in this brochure are typical for wrought products
and should not be regarded
Mechanical Properties
| Ultimate Tesile
Strength, ksi |
116 min. |
| 0.2% Offset Yield Strength
0.2%, ksi |
80 min. |
| 0.1% Offset Yield Strength
0.2%, ksi |
91 min. |
| Elongation in 2inches, % |
15 min. |
| Hardness Rockwell C |
32 max. |
| Impact Energy, ft.-lbs. |
74 min. |
|
Low Temperature Impact Properties
| Temperature
ÅF |
RT |
34 |
-4 |
-40 |
| Ft.-lbs. |
162 |
162 |
155 |
140 |
| Temperature ÅF |
-76 |
-112 |
-148 |
-320 |
| Ft.-lbs. |
110 |
44 |
30 |
7 |
|
Elevated Temperature Tensile
Properties
| Temperature
ÅF |
68 |
212 |
302 |
392 |
482 |
| 0.2% Offset Yield Strength,
ksi |
80 |
65 |
61 |
58 |
55 |
| Ultimate Tensile Strength,
ksi |
116 |
101 |
98 |
95 |
94 |
|
Physical Properties
| Density |
lb/in3 |
0.28 |
| Modulus of Elasticity |
psi x 106 |
29 |
| Coefficient of Thermal Expansion
68-212ÅF/ÅF |
x10-6/ÅF |
7.2 |
| Thermal Conductivity |
Btu/h ft ÅF |
8.7 |
| Heat Capacity |
Btu/lb/ÅF |
0.12 |
| Electrical Resistivity |
W-in x 10-6 |
31.5 |
|
|
Processing
Hot
Forming
SAF 2507 should be hot worked between 1875ÅF and 2250ÅF.
This should be followed by a solution anneal at 1925ÅF minimum
and a rapid air or water quench.
Cold Forming
Most of the common stainless steel forming methods can be
used for cold working SAF 2507. The alloy has a higher yield
strength and lower ductility than the austenitic steels
so fabricators may find that higher forming forces, increased
radius of bending, and increased allowance for springback
are necessary. Deep drawing, stretch forming, and similar
processes are more difficult to perform on SAF 2507 than
on an austenitic stainless steel. When forming requires
more than 10% cold deformation, a solution anneal and quench
are recommended.
Heat Treatment
SAF 2507 should be solution annealed and quenched after
either hot or cold forming. Solution annealing should be
done at a minimum of 1925ÅF. Annealing should be followed
immediately by a rapid air or water quench. To obtain maximum
corrosion resistance, heat treated products should be pickled
and rinsed.
|
| Welding
SAF 2507 possesses good weldability and can
be joined to itself or other materials by shielded metal
arc welding (SMAW), gas tungsten arc welding (GTAW), plasma
arc welding (PAW), flux cored wire (FCW), or submerged arc
welding (SAW). 2507/P100 filler metal is suggested when
welding SAF 2507 because it will produce the appropriate
duplex weld structure.
Preheating of SAF 2507 is not necessary except to prevent
condensation on cold metal. The interpass weld temperature
should not exceed 300ÅF or the weld integrity can be adversely
affected. The root should be shielded with argon or 90%
N2/10% H2 purging gas for maximum
corrosion resistance. The latter provides better corrosion
resistance.
If welding is to be done on only one surface and post weld
cleaning is not possible, GTAW is suggested for root passes.
GTAW or PAW should not be done without a filler metal unless
post weld cleanup is possible. A heat input of 5-38 kJ/in.
should be used for SMAW or GTAW. A heat input of about 50kJ/in.
can be used for SAW.
|
NOTE
2205 Code Plus Two is a registered trademark of AvestaPolarit,
Inc. 254 SMO and 654 SMO are registered trademarks of AvestaPolarit
Stainless. SAF 2304 and SAF 2507 are registered trademarks
of Sandvik AB.
This technical data and information represents our best
knowledge at the time of printing. However, it may be subject
to some slight variations due to our ongoing research program
on corrosion resistant grades.
We, therefore, suggest that information be verified at time
of inquiry or order. Furthermore, in service, real conditions
are specific for each application. The data presented here
is only for the purpose of description and may only be considered
as guarantees when our Company has given written formal
approval. |
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